Which of the following molecule is not ir active

Asked by admin @ in Chemistry viewed by 297 People

Which of the following molecules would show rotational spectrum: Br2, CO,

N2, HBr and CS2? Why? Among them which are IR active? Calculate their
total mode of vibrations

Answered by admin @


Explanation:

A molecule has translational and rotational motion as a whole while each atom has it's own motion. The vibrational modes can be IR or Raman active. For a mode to be observed in the IR spectrum, changes must occur in the permanent dipole (i.e. not diatomic molecules). Diatomic molecules are observed in the Raman spectra but not in the IR spectra. This is due to the fact that diatomic molecules have one band and no permanent dipole, and therefore one single vibration. An example of this would be O2 or N2. However, unsymmetric diatomic molecules (i.e. CN) do absorb in the IR spectra. Polyatomic molecules undergo more complex vibrations that can be summed or resolved into normal modes of vibration.

The normal modes of vibration are: asymmetric, symmetric, wagging, twisting, scissoring, and rocking for polyatomic molecules.

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