What will be the ph of 1.0 m ammonium formate


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What will be the pH of 1.0 M ammonium formate solution, if Ka = 1 *10^-4 acid Kb = 1 *10^-5:

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Answer: pH pf ammonium formate solution will be 6.5

Explanation: Ammonium formate is a salt of weak acid (formic acid) and strong base (ammonia). We can calculate pH by using the formula:

pH=\frac{1}{2}(pK_w+pK_a-pK_b)

We are given values of K_a\text{ and }K_b

K_a=1\times10^{-4}\\K_b=1\times10^{-5}

Relation between pK_a\text{ and }K_a is

pK_a=-logK_a

pK_a=-log(0.0004)

pK_a=4

similarly, pK_b=5

and pK_w=14  (known)

Putting values in equation 1, we get

pH=\frac{1}{2}(14+4-5)

pH = 6.5


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